Preparation of ultra-fine copper powder and its lead-free conductive thick film

In this paper, non-agglomerated monodispersed ultra-fine copper metallic powders have been synthesized with chemical reduction method. Fine lead-free glass powders were also prepared by solid synthesis process. Thick film paste prepared by above-mentioned copper metallic powders and lead-free glass powders was applied as conductive paste of MLCC. Mixture of glass and zinc oxide give the thick film a high adhesion strength which is attributed to the rough interface from interfacial reaction between glass and chip, and a good densification. Diffusion of metal between copper thick film and nickel thick film is clear. Ni-Cu solid solution appears under high temperature firing.     

陈垃圾土的压缩性试验研究

首先介绍了重庆市主城区填埋场的现状，论述了深入研究陈垃圾土压缩特性的重要性。作者在简要总结了采样场内陈垃圾土的基本物理性质后。通过室内侧限压缩试验(亦称固结试验)，得出了描述陈垃圾土压缩性质的基本参数，如αv、Es、mv和Cc等，试验表明陈垃圾土是一种不同于常见土类的高压缩性欠固结土，试验结果可为填埋场再利用和已封闭填埋场的沉降计算提供依据。     

沸石处理稀土生产中氨氮废水的实验研究

为实现稀土生产中氨氮废水的治理,选用天然吸附材料沸石,用它的吸附和离子交换性能来处理稀土生产中的氨氮废水,采用静水和动水两种方法进行实验。实验结果表明,用沸石处理工业废水中的氨氮,去除率达50%以上。     

企业实施精益生产的探讨

通过描述造成企业经济效益差的原因之一——浪费，提出了如何实施精益生产，消除企业浪费，以提高企业经济效益．     

用磷铝杂原子固体酸催化剂合成马来酸二丁酯

以自制的磷铝杂原子固体酸催化剂催化合成了马来酸二丁酯，考察了反应时间、醇酸摩尔比、带水剂用量、催化剂用量等对酯化率的影响；同时考察了催化剂的重复使用性。对酯化产物物理性能进行了测试，其实测值与文献值相符。     

New approach to environmentally benign epoxidation: the solid-phase-system using urea–H2O2 and recyclable dodecatungstate on apatite

On the basis of new concept using a solid disperse phase we have developed an efficient catalytic solid-phase-system for epoxidations of alkenes using urea–hydrogen peroxide (urea–H₂O₂) complex and cetylpyridinium dodecatungstate ((CetylPy)₁₀[H₂W₁₂O₄₂]) catalyst on fluorapatite (FAp). The recovered solid catalyst phase was reused to keep the catalytic activity after several times. In the conceptual idea it is a key point that in situ solid-phase-activation of the catalyst with urea–H₂O₂ proceeds to form microcrystals of the active species dispersed on the solid phase. The dispersion of the catalyst on FAp in the case of tungstic acid (H₂WO₄) was suggested by EPMA analysis. We proposed the peroxo type of species keeping the parent polyoxometalate framework as novel active species from FT-IR spectroscopic studies. FAp phase plays important roles of dispersing the active species on its surface to have high catalytic activity and of stabilizing the active species to lead to high reusability.     

Municipal solid waste conversion to energy

In recent years it has been recognised by an increasing number of nations that there is considerable energy potential within MSW. As a result many countries have established R,D& D programmes to examine methods of exploiting this potential. The IEA's MSW Conversion Activity was set up in 1986 to provide an infrastructure for sharing information and co-ordinating work in this area internationally. This Activity was extended in 1989 and currently a total of 9 nations participate in it.

To cope with the wide scope of the area (encompassing both biological and thermal processing of MSW) the Activity was divided into three subgroups or Expert Working Groups (EWGs). Each of these dealt with a distinct area of expertise:

1. •Downstream effects of source separation and screening of MSW

2. •Sampling and analytical protocols

3. •Landfill gas

In addition to these groups a central secretariat based at Harwell (UK) has provided guidance, established and administered databases of contacts and produced a series of national reports.

This paper describes the achievements of the Activity and discusses work proposed for the future.     

ICP－AES法测定工业废水中铬镍锌铜镉含量

研究了采用ＩＣＰ－ＡＥＳ田法测定工业废水中Ｃｒ、Ｎｉ、Ｚｎ、Ｃｕ和Ｃｄ含量的试验方法。该法用于国家标准水样和工业废水样品分析，获得满意的结果，并产生了经济和社会效益。     

鸡冠咀金矿废水污染预测及控制标准的探讨

本文以鸡冠咀金矿废水污染为例,论述了复杂水环境的预测模式选择和参数确定;并对水质标准进行了探讨;提出了鸡冠咀金矿废水排放的控制标准。     

An analysis of the electrical conductivity in BaSO4-added Ag2SO4 solid electrolyte system

The compositions (1 −x)Ag₂SO₄−(x)BaSO₄, wherex=0·01 to 0·6, were prepared by slow cooling of the melt. The extent of the solid solubility of Ba²⁺ in Ag₂SO₄ was determined by X-ray powder diffraction and scanning electron microscopy. The bulk conductivity of each sample was obtained using a detailed impedance analysis. The partial substitution of Ba²⁺ results in the enhancement of conductivity in compliance with the classical aliovalent doping theory. A simplistic model based on lattice distortion (expansion) due to partial substitution of Ag⁺ by the bigger Ba²⁺ has been considered to explain enhanced conductivity. Beyond solid-solubility limit (5·27 mole%) the BaSO₄-dispersed Ag₂SO₄ conductivity follows the usual trend seen in binary systems. An increase in conductivity in this case is discussed in the light of interfacial reactions and surface defect chemistry. The maximum conductivity in 20 mole% BaSO₄ dispersed Ag₂SO₄ is due to percolation threshold.